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题名: Unconventional Aluminum Ion Intercalation/Deintercalation for Fast Switching and Highly Stable Electrochromism
作者: Tian, YY(田亚洋); Zhang, WK(张炜坤); Cong, S(丛杉); Zheng, YC; Geng, FX; Zhao, ZG(赵志刚)
通讯作者: Tian, YY (田亚洋)
刊名: ADVANCED FUNCTIONAL MATERIALS
发表日期: 2015
DOI: 10.1002/adfm.201502638
卷: 25, 期:36, 页:7
收录类别: SCI
部门归属: 先进材料研究部
英文摘要: Electrochromic devices have many important commercial applications ranging from electronic paper like displays, antiglare rear-view mirrors in cars, to energy-saving smart windows in buildings. Monovalent ions such as H+, Li+, and Na+ are widely used as insertion ions in electrochromic devices but have serious limitations such as instability, high-cost, and hard handling. The utilization of trivalent ions as insertion ions has been largely overlooked probably because of the strong electrostatic interactions between ions and intercalation framework and the resulted diffi culties of intercalation. It is demonstrated that the trivalent ion, Al3+, can be used as effi cient insertion ion by using metal oxide hosts in nanostructured form, which brings the desired fast-switch, high-contrast, and high-stability as well to electrochromic devices. Differing from the usual structure degradation by repeated guest intercalation/deintercalation, the Al3+ insertion introduces strong electrostatic forces, which on some degree stabilize the crystal structure and consequently yield much enhanced performances.
语种: 英语
JCR小类分区: 一区
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内容类型: 期刊论文
URI标识: http://ir.sinano.ac.cn/handle/332007/3308
Appears in Collections:先进材料研究部_赵志刚团队_期刊论文

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Recommended Citation:
Tian, YY,Zhang, WK,Cong, S,et al. Unconventional Aluminum Ion Intercalation/Deintercalation for Fast Switching and Highly Stable Electrochromism[J]. ADVANCED FUNCTIONAL MATERIALS,2015,25(36):7.
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文件名: Unconventional Aluminum Ion Intercalation_Deintercalation for Fast Switching and Highly Stable Electrochromism.pdf
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