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题名: 2D Confined-Space Assisted Growth of Molecular-Level-Thick Polypyrrole Sheets with High Conductivity and Transparency
作者: Yang, Y; Wang, D; Wu, YJ; Tian, XR; Qin, HL; Hu, L; Zhang, T(张珽); Ni, WH(倪卫海); Jin, J(靳健)
通讯作者: Zhang, T(张珽) ; Jin, J(靳健)
刊名: MACROMOLECULAR RAPID COMMUNICATIONS
发表日期: 2016
DOI: 10.1002/marc.201500698
卷: 37, 期:7
收录类别: SCI ; EI
文章类型: 期刊论文
部门归属: 纳米研究国际实验室
英文摘要: Herein, the use of a 2D soft template system composed of hundred-nanometer-thick water/ethanol mixed layers sandwiched by lamellar bilayer membranes of a self-assembled amphiphilic molecule to produce ultrathin polyprrole (PPy) with a uniform thickness as thin as 3.8 nm and with large dimensions (>2 mu m(2)) is presented. The obtained PPy nanosheets exhibit regioregularity with ordered chain alignment where the polymer chains in the nanosheets produced are well aligned with a clear interchain spacing as confirmed by small-angle X-ray scattering measurement. The molecular-level-thick PPy nanosheets exhibit extremely high conductivity up to 1330 S m(-1), thanks to the ordered alignment of polymer chains in the nanosheets, and a high transparency in both the visible region (transmittance >99%) and near-infrared region (transmittance >93%).
关键词[WOS]: CONJUGATED POLYMERS ; SURFACE ; FILMS ; POLYMERIZATION ; PERFORMANCE ; ASSEMBLIES ; NANOSHEETS ; INTERFACE ; ALIGNMENT ; TEMPLATE
语种: 英语
JCR小类分区: 一区
WOS记录号: WOS:000374002900004
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinano.ac.cn/handle/332007/4586
Appears in Collections:纳米研究国际实验室_张珽团队_期刊论文

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Recommended Citation:
Yang, Y,Wang, D,Wu, YJ,et al. 2D Confined-Space Assisted Growth of Molecular-Level-Thick Polypyrrole Sheets with High Conductivity and Transparency[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2016,37(7).
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