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题名: Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries
作者: Li, WF(李宛飞); Cheng, S(程双); Wang, J; Qiu, YC(丘勇才); Zheng, ZZ(郑召召); Lin, HZ(蔺洪振); Nanda, S; Ma, Q; Xu, Y; Ye, FM(叶方敏); Liu, MN(刘美男); Zhou, LS(周莉莎); Zhang, YG(张跃钢)
通讯作者: Zhang, YG(张跃钢)
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
发表日期: 2016
DOI: 10.1002/anie.201600256
卷: 55, 期:22
收录类别: SCI ; EI
文章类型: 期刊论文
部门归属: 纳米研究国际实验室
英文摘要: Most simple magnesium salts tend to passivate the Mg metal surface too quickly to function as electrolytes for Mg batteries. In the present work, an electroactive salt [Mg-(THF)(6)][AlCl4](2) was synthesized and structurally characterized. The Mg electrolyte based on this simple mononuclear salt showed a high Mg cycling efficiency, good anodic stability (2.5V vs. Mg), and high ionic conductivity (8.5 mScm(-1)). Magnesium/sulfur cells employing the as-prepared electrolyte exhibited good cycling performance over 20 cycles in the range of 0.3-2.6 V, thus indicating an electrochemically reversible conversion of S to MgS without severe passivation of the Mg metal electrode surface.
关键词[WOS]: RECHARGEABLE MG BATTERIES ; LITHIUM-SULFUR BATTERIES ; LI-S BATTERIES ; PERFORMANCE ; GRAPHENE ; SEPARATOR ; SALTS
语种: 英语
JCR小类分区: 一区
WOS记录号: WOS:000377921200006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinano.ac.cn/handle/332007/4800
Appears in Collections:纳米研究国际实验室_张跃钢团队_期刊论文

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Recommended Citation:
Li, WF,Cheng, S,Wang, J,et al. Synthesis, Crystal Structure, and Electrochemical Properties of a Simple Magnesium Electrolyte for Magnesium/Sulfur Batteries[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(22).
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