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题名: Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes
作者: Cao, RW; Zhang, JL; Zhou, H; Yang, HM; Jiang, GX(蒋高喜)
通讯作者: Jiang, GX
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2016
DOI: 10.1039/c5ob02653a
卷: 14, 期:7
收录类别: SCI ; EI
文章类型: 期刊论文
部门归属: 先进材料研究部
英文摘要: A highly atom-economical allylation of oxindoles with vinyl cyclopropanes catalyzed by Pd(PPh3)(4) has been developed, setting up a practical venue for the installation of an all-carbon quaternary center at the 3-position in oxindoles under mild reaction conditions. Importantly, the reaction proceeded well without any additives and no waste was produced, affording linear products with high regioselectivities (>20:1). Enantioselective allylic alkylation has also been realized to provide the desired products in good yields and 35% ee.
关键词[WOS]: ENANTIOSELECTIVE 3+2 CYCLOADDITION ; ASYMMETRIC ALLYLIC ALKYLATION ; DONOR-ACCEPTOR CYCLOPROPANES ; BAYLIS-HILLMAN ADDUCTS ; DIPHOSPHINE LIGANDS ; SYNTHETIC REACTIONS ; ALLYLBORONIC ACIDS ; VINYLCYCLOPROPANES ; CONSTRUCTION ; NUCLEOPHILES
语种: 英语
JCR小类分区: 二区
WOS记录号: WOS:000370878800006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinano.ac.cn/handle/332007/4925
Appears in Collections:先进材料研究部_离职团队_期刊论文

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Recommended Citation:
Cao, RW,Zhang, JL,Zhou, H,et al. Palladium-catalyzed highly atom-economical allylation of oxindoles with vinyl cyclopropanes[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2016,14(7).
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